The problem of ore-processing plants’ waste and man-made mineral formations (MMF) disposal is very important for the Republic of Kazakhstan. The research of various ore types (gold, polymetallic, iron-bearing) MMF from a number of Kazakhstan’s deposits using a complex physical and chemical methods showed, that the waste’s main components are silicate and aluminosilicate compounds that can be used to produce adsorbents for fine purification of industrial and natural waters from heavy metals. According to the research, the only MMF of gold and polymetallic ores are environmentally safe for this purpose. Based on the samples, selected with thermal and acid methods, using phosphoric extraction acid, was synthesized a set of silicophosphate products. It was found, that under the optimum conditions, allowing to obtain insoluble porous products with high sorption activity, high the about 10-11 % of final product have the mechanical strength and a heat treatment temperature of 400°C. It is shown, that the dynamic adsorption capacity of synthesized silicophosphate sorbents to copper cations is 1,85  2,5 mg =  Cu2+/g. This allows conditioning of water for domestic and drinking purposes, cleaning waste water of heavy metal cations from enterprises, reduce the MMF deposits, or use the latter for the concentration of heavy metals to the level of economically viable industrial processing in the future.

Deng, S. (2015). Sorbent Technology. Encyclopedia of Chemical Processing, 2825-2845.

Developments in Mineral Processing. (2000),13 Proceedings of the XXI International Mineral Processing Congress. July 23-27. Rome, Italy. Elsevier Science, Amsterdam, 364-369.

Dinamic Adbsorbents, Inc. (2015, March 15). DAI Products. More about Adsorption, Desiccants and Sorbents. Direct access: http://dynamicadsorbents.com/products2.htm

Gelfman, M. I., Tarasov, Yu., Shevchenko, T. & Mandziy, M. R. (2002). The study of sorption characteristics of natural and modified sorbents based on silica-alumina raw material. Chemical Industry, 8, 50 – 56

Government Report. (1988). The inventory of resources and prospects of complex use of non-ferrous metal waste products. Almaty, Kazakhstan, 64 p.

Government Report. (1989). The inventory of resources and prospects of complex use of ore and waste ferrous metals, Almaty, Kazakhstan, 54 p.

Government Report. (2016). Plans for the development of the production of mineral fertilizers on the branches of LLP “Kazphosphate” 2016-2020, Almaty, Kazakhstan, 36 p.

Gubaidulina, G. M., Fishbein, O., Kapralova, V. I., Zhakitova, G. U. & Zhusupova, L. A. (2005). Optimization of technological parameters and conditions of silico-aluminophosphate sorbents. Science News of Kazakhstan. Science & Technology Digest, 2(85), 66-71.

Iler, R. K. (1979). The Chemistry of Silica: Solubility, Polymerization, Colloid and Surface Properties and Biochemistry of Silica. Wiley-Interscience.

Marchenko, L. A., Bokovikova, T. N., Poluliakhov, N. N., & Privalov, N. M. (2002). Sorption extraction of heavy metal ions in filtering wastewater through the activated aluminosilicate adsorbent. Nature. and tehn. science, 2. 36-38.

Matis, K. A., & Mavros, P. (1991). Froth Lotation Part II. Removal of Particulate Matter. Separation  and Purification Methods, 20(2), 163-198.

National report on the state of the environment and use of natural resources for the 2011 - 2014 years (2011). Direct access: http://hdr.undp.org/sites/default/files/reports/271/hdr_2011_en_complete.pdf

Nevskaya, M. A & Marinina, O. A. (2015). Regulatory Aspects of Mining Waste Management in the Russian Federation. Biosci. Biotechnol. Res. Asia, 12(3), 174-184.

Pat. 20050090390 US, A1. Pub.No 27.10.2003 , Pub.dat. Apr. 28. 2005 N. Venkatathri et al. Process for the preparation of porous crystalline silicoaluminophosphate molecular sieves.

Pat. 2024430 Russia, A method of producing crystalline silico-aluminophosphates: 1994. IPC5 of 01 B 33/26 / S.P. Zhdanov, Feoktistov N.N., Smirnova E.I., Vasilyeva E.A.; Institute of Silicate Chemistry of the Academy of Sciences of the USSR. Ann. 26.06.91. Publ.15.12.94.№2

Pat. 6413492 USA, Method of forming high aluminum aluminosilicate zeolites : IPC7 C 01 B 39/02%C 01 B 39/14; Engilhard Corp., Kuznicki Steven M., Langner Tadeusz W., Curran Jacqueline S., Bell Valerie A. - N 09/533606; Ann. 23.03.2000; Publ. 02.07.2002; CIS 423/700.

Pat. 6416732 USA, Method of forming aluminosilicate zeolites : IPC7 C 01 B 39/02%C 01 B 39/18; Engelhard Corp., Curran Jacqueline S., Bell Valerie A., Kuznicki Steven M., Langner Tadeusz W. - N 09/533707; Announced 23.03.2000; Published 09.07.2002; CIS 423/700.

Shilina, A. S. & Milinchuk, V. K. (2010). The sorption purification of natural and industrial waters from cations of heavy metals and radionuclides, a new type of high temperature aluminosilicate adsorbent. Sorption and chromatographic processes, 10(2), 237-245

Su-Hsia, Lin, & Ruey-Shin, Juang. (2002). Heavy metal removal from water by sorption using surfactant-modified montmorillonite. Hazardous Mater, 92(3), 315-32

Sumer, O. & Yuda, Ju. (2001). Synthesis of crystalline ZSM-5 type zeolites utilizing primary monoalkylamines. 1. Characterization. Energy Sources, 23(5), 475-485.

Uberoi, M., & Shadman, F. (1991). Fundamentals of Heavy Metal Removal with Dry Sorbents. New York. Symposium on Clean Energy, 1742-1749.

Uddin, M. N., Shah, N. M., Hossain, M. A., & Islam, Md. M. (2014). Copper and Mercury in Food, Biological and Pharmaceutical Samples. American Journal of Analytical Chemistry, 5, 838-850

Yessirkepova, A. M., Missyul, E. E., & Sabdenova, Zh. O. (2015). The Level of Development of the Industrial Sector in Kazakhstan as a Major Source of Waste. The virtual project of the ІХ Astana Economic Forum, 114-120.